In the final Yastremsky dated 24-th racket of the world Wang Qiang, which in the 1/4 final easily beat Elina Svitolina, and in the semifinals in three sets to clinch the victory over the former first racket of the world Garbine Muguruza.
"It was (the) toughest game", she said.
Earlier Saturday, Wang had knocked out top-seeded Elina Svitolina of Ukraine 6-2, 6-4 in a quarterfinal match that was paused Friday due to rain, with Wang leading 6-2, 6-5. "Every tournament I play, every match I play my goal is to win, to ideal myself, to get experience and to win one day a Grand Slam", she said.
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"I had nothing to lose against her - she's a very good player", Wang said.
Fifth-seeded Italian Camila Giorgi won her second career title, beating Russian qualifier Ekaterina Alexandrova 6-3, 6-1 in the final in Linz, Austria.
Garbine Muguruza awaits the victor of that tie after she reached her first semi-final since the French Open in June.
China's Zhang Shuai looked in ominous form at the Hong Kong Open on Friday as she swatted aside last year's runner-up Daria Gavrilova in straight sets - and said she was growing in confidence with every victory.
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Svitolina entered this week as one of five players still in contention to earn a place in the eight-player WTA Finals in Singapore.
In order to do that, she would need to play the Moscow tournament next week. "I just went for it", Wang said at the close of her marathon day. "After match point I fell on the floor because I felt so relaxed, that was my instinct to go and lie because I needed to put it away, the emotions". She's yet to drop a set this week en route to the semifinals.
"I want to repeat it all from the first match".
Zhang, who has won two career WTA singles titles, will be favourite to win against 18-year-old Yastremska, now ranked 102.
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The 26-year-old, who also reached the semifinals at Wuhan and Beijing, fought from a set down and 4-1 down in the third to defeat fourth-seeded Muguruza, 6-7 (5), 6-4, 7-5. "I even started to cry a little bit".